Coalition for Responsible Waste Incineration



FURNACES, BOILERS AND INCINERATORS

Technical Issue

Hazardous materials and wastes are burned in different processing units for different purposes. These include material recovery in furnaces, energy recovery in boilers, and waste treatment in incinerators. It is important to distinguish the primary purposes of different units and the types of materials or wastes being burned to encourage uses of most environmentally preferable management alternatives.

Technical Background

The objective of hazardous waste management is to both minimize waste generation and maximize waste control. Waste reduction, including energy and material recoveries, is applied to materials before they are discarded as wastes; waste control, including storage, treatment and disposal, is applied after discard. Recovery and treatment processes are applied immediately to minimize long-term adverse effects of waste constituents and perpetual care required by subsequent disposal. Thermal processes comprise both recovery and treatment alternatives. Waste minimization is encouraged through recovery of material and energy values before destruction of combustible constituents by incineration. Thermal processes reduce volume and/or hazard of both materials or wastes, but do not completely eliminate ultimate disposal. Noncombustible residues of no value must be disposed as treated solid residues and dispersed as treated gaseous and liquid discharges.

All thermal processes involve application of controlled flame or indirect heating at high temperature to enhance concentration, separation, or chemical conversion of constituents. They are integral to manufacture of basic products. Glass, cement, metals, pigments, and medicinals are ancient examples of thermally produced materials. Modern examples include chemical production, petroleum refining, metal smelting, cement manufacture, and glass fabrication. Thermal processing is used extensively for chemical production, energy and material recovery, and waste treatment. Examples include production of carbon black, carbon dioxide, and hydrochloric acid; combustion of fuels; recoveries of brines, catalysts, and solvents; and destruction of combustible organic constituents or conversion of inorganic constituents of waste to more stable oxides through incineration.

Alternatives include several self contained, high-temperature combustion processes conducted in thermal processing units:

  1. Waste reduction in chemical processing facilities,
  2. Energy recovery in industrial boilers,
  3. Material recovery in industrial furnaces, and
  4. Waste treatment in industrial incinerators.
Thermal processes in the chemical industry encompass a variety of different process units, commercial purposes, and inputs and outputs:

Unit -- Processing
Purpose -- Chemical production
Input -- Raw materials, intermediates, by-products
Output -- Products, secondary materials, fuels, wastes

Unit -- Furnace
Purpose -- Material recovery
Input -- Undiscarded materials, spent solvents, spent catalysts, other spent materials
Output -- Reclaimed materials, fuels, wastes

Unit -- Boiler
Purpose -- Energy recovery
Input -- Fossil fuels, refuse-derived fuels, ignitable wastes
Output -- Recovered energy, wastes

Unit -- Incinerator
Purpose -- Waste treatment
Input -- Discarded materials, solid wastes, hazardous wastes
Output -- Reduced waste volumes, reduce waste toxicity

Chemical processing facilities are designed for conversion of raw materials into finished products. Furnaces are designed for conversion of secondary materials into recoverable by-products. Boilers are designed for combustion of fuels and recovery of energy. Incinerators are designed for reduction of waste volume and hazard. All processes are conducted within totally enclosed engineered devices.

A single combustible substance may be a raw material, a process intermediate, a fuel, and/or a waste, and be any or all four at any given time on the same site. For example, petroleum hydrocarbons are naturally derived, refined as fuels, recombined as polymers and other useful items, and ultimately discarded as wastes. Crude oil, gasoline, benzene, and flammable solvent waste are each perceived differently.

Incineration has multiple purposes: (i) reduction in volume of solid wastes, (ii) conversion of hazardous constituents into non-hazardous forms, (iii) selective removal of gaseous and water-soluble products of combustion for further treatment, and (iv) formation of stable noncombustible solid residues for ultimate disposal. Treatment of combustible constituents is immediate thereby minimizing perpetual care of land disposal. Incinerators are designed and operated for specific functions. A medical waste incinerator (MWI) burns hospital and medical wastes. A municipal waste combustor (MWC) burns solid wastes from municipalities. A hazardous waste incinerator (HWI) burns primarily hazardous wastes of industrial origin. All three usually burn non-hazardous solid wastes (trash, garbage). The MWI may be owned and operated by a large medical facility. The MWC is often publicly owned and supported by tax funds and/or user fees. The HWI may be owned and operated exclusively by a waste generator. All three types may also be commercial incinerators, i.e., owned and operated by a waste management firm in which wastes from second parties are burned for a fee.

The primary functions of boilers, furnaces, and incinerators are significantly different. The types of wastes burned by incinerators are quite different. Emission control devices and the management of gaseous emissions, wastewater, and solid residuals are different. Consequently, environmental regulations that have evolved are different. However, all three are stringently regulated under the Resource Conservation and Recovery Act (RCRA). All combustion sources are also subject to provisions of the Clean Air Act (CAA) and the Clean Water Act (CWA).

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